MN007 Fundamentals of Defect Chemistry

6 ECTS - 3-0 Duration (T+A)- . Semester- 3 National Credit

Information

Code MN007
Name Fundamentals of Defect Chemistry
Term 2024-2025 Academic Year
Semester . Semester
Duration (T+A) 3-0 (T-A) (17 Week)
ECTS 6 ECTS
National Credit 3 National Credit
Teaching Language İngilizce
Level Doktora Dersi
Type Normal
Mode of study Yüz Yüze Öğretim
Catalog Information Coordinator


Course Goal / Objective

Investigation of defects in materials in nanocatalytic processes, formation of defects in a controlled manner and demonstration of defect determinations by electron paramagnetic resonance spectroscopy.

Course Content

Crystalline materials, defect types, transport mechanisms in crystalline materials, controlling defect chemistry: Atmosphere, temperature, and doping effects, defect related transport in important applications and processes, intrinsic electronic disorder and non-stoichiometry, extrinsic electronic disorder and non-stoichiometry, interactions with the gasous ambient, defects in functional ceramics, defect interpretation methods, EPR spectroscopy in defect interpretation

Course Precondition

Solid State Physics

Resources

1. D. M. Smyth,The defect chemistry of metal oxides, New York : Oxford University Press, 2000

Notes

2. M. S. Seltzer, R. I. Jaffee, Defects and Transport in Oxides, Springer-Verlag, US, 1974 3. F.A. Kröger, The Chemistry of Imperfect Crystals, North-Holland, Amsterdam, Wiley, 1964 4. F.A. Kröger, H.J. Vink, Solid State Physics (eds F. Seitz and D. Turnbell) 3, 307, Academic Press, New York, 1956 5. D.F. Shriver and P.W. Atkins Inorganic Chemistry, 3rd ed. Oxford Univ. Press., Oxford, 1999


Course Learning Outcomes

Order Course Learning Outcomes
LO01 Explains ordered and disordered structures in nanomaterials.
LO02 Identifies different types of defects in nanomaterials.
LO03 Explain the transport mechanisms from crystal materials.
LO04 Explains the defects in functional ceramics.
LO05 Evaluates some defect types by EPR spectroscopy method.
LO06 Identifies the relationship between defects and material properties.


Relation with Program Learning Outcome

Order Type Program Learning Outcomes Level
PLO01 Bilgi - Kuramsal, Olgusal Based on the qualifications gained during PhD studies, develops and deepens the current and advanced knowledge in the area by unique means of thinking and / or research at mastery level and comes up with original definitions which bring about novelty to the area. 3
PLO02 Beceriler - Bilişsel, Uygulamalı Can effectively use the equipment used in the field.
PLO03 Yetkinlikler - Bağımsız Çalışabilme ve Sorumluluk Alabilme Yetkinliği Selects experimental measurement methods of various physical quantities and uses instruments in accordance with their sensitivity limits. 3
PLO04 Yetkinlikler - Alana Özgü Yetkinlik Interprets experimental and observational results.
PLO05 Yetkinlikler - Öğrenme Yetkinliği Can draw conclusions from the information obtained during the preparation for the PhD qualifying exam.
PLO06 Bilgi - Kuramsal, Olgusal Can interpret the information acquired about the field orally and in writing. 4
PLO07 Bilgi - Kuramsal, Olgusal Uses mathematical methods related to the field of study. 3
PLO08 Yetkinlikler - Bağımsız Çalışabilme ve Sorumluluk Alabilme Yetkinliği Have knowledge about the logic, design, conclusion and dissemination of results of scientific research. 4
PLO09 Bilgi - Kuramsal, Olgusal Uses the theoretical and applied knowledge gained in the field of materials and nanotechnology at the level of expertise. 3
PLO10 Yetkinlikler - Bağımsız Çalışabilme ve Sorumluluk Alabilme Yetkinliği Gains high-level skills in using research methods in studies related to materials science and nanotechnology.
PLO11 Bilgi - Kuramsal, Olgusal Develops a scientific method that brings innovation to science.
PLO12 Yetkinlikler - Alana Özgü Yetkinlik Makes critical analysis, synthesis and evaluation of new ideas related to the field. 4
PLO13 Yetkinlikler - Bağımsız Çalışabilme ve Sorumluluk Alabilme Yetkinliği Can carry out independent research on a specific topic related to materials and nanotechnology. 3
PLO14 Yetkinlikler - İletişim ve Sosyal Yetkinlik Be able to lead in the execution of interdisciplinary studies.
PLO15 Yetkinlikler - Öğrenme Yetkinliği Follows the developments in the her/his field of study and constantly renews herself/himself.
PLO16 Bilgi - Kuramsal, Olgusal Calculate the predictions of the theories and compare them with the experimental results.
PLO17 Yetkinlikler - Öğrenme Yetkinliği Comprehends the interdisciplinary interaction that the field of study is related to.
PLO18 Yetkinlikler - Alana Özgü Yetkinlik He/she shares his/her own ideas and suggestions regarding the problems in the field of study with groups in and outside the field by supporting them with quantitative and qualitative data.
PLO19 Yetkinlikler - Bağımsız Çalışabilme ve Sorumluluk Alabilme Yetkinliği Can develop original solutions for problems in the field.
PLO20 Yetkinlikler - Bağımsız Çalışabilme ve Sorumluluk Alabilme Yetkinliği Can prepare a scientific article and publish scientific articles in international refereed journals.


Week Plan

Week Topic Preparation Methods
1 Crystalline materials and defect types Intorduction to crystallography Öğretim Yöntemleri:
Anlatım
2 Lattice Defects 1st week topics Öğretim Yöntemleri:
Anlatım, Soru-Cevap
3 Defect Chemistry and Equilibria previous week topics Öğretim Yöntemleri:
Anlatım, Soru-Cevap, Alıştırma ve Uygulama
4 Defect Complexes and Associates previous week topics Öğretim Yöntemleri:
Anlatım, Soru-Cevap, Alıştırma ve Uygulama
5 Controlling defect chemistry: Atmosphere, temperature, and doping effects previous week topics Öğretim Yöntemleri:
Anlatım, Soru-Cevap
6 Transport mechanisms in crystalline materials previous week topics Öğretim Yöntemleri:
Anlatım, Soru-Cevap, Örnek Olay
7 Defect related transport in important applications and processes previous week topics Öğretim Yöntemleri:
Anlatım, Soru-Cevap, Örnek Olay
8 Midterm exam previous week topics Ölçme Yöntemleri:
Yazılı Sınav
9 Intrinsic & Extrinsic Electronic Disorder and Non-stoichiometry previous week topics Öğretim Yöntemleri:
Anlatım, Alıştırma ve Uygulama, Örnek Olay
10 Interactions with the gasous ambient previous week topics Öğretim Yöntemleri:
Anlatım, Alıştırma ve Uygulama, Örnek Olay
11 Defects in functional ceramics previous week topics Öğretim Yöntemleri:
Anlatım, Soru-Cevap, Örnek Olay
12 Defect interpretation methods previous week topics Öğretim Yöntemleri:
Anlatım, Soru-Cevap, Örnek Olay
13 Electron Paramagnetic Resonance (EPR) Spectroscopy in defect interpretation previous week topics Öğretim Yöntemleri:
Anlatım, Alıştırma ve Uygulama, Örnek Olay
14 Advanced Electron Paramagnetic Resonance (EPR) Spectroscopic methods previous week topics Öğretim Yöntemleri:
Anlatım, Soru-Cevap, Alıştırma ve Uygulama
15 Project Presentation 1st week Research on various sources according to the selected subject Ölçme Yöntemleri:
Sözlü Sınav, Proje / Tasarım, Performans Değerlendirmesi
16 Final Project Presentations Research on various sources according to the selected subject Ölçme Yöntemleri:
Sözlü Sınav, Proje / Tasarım, Performans Değerlendirmesi
17 General overview previous week topics Öğretim Yöntemleri:
Anlatım, Soru-Cevap


Student Workload - ECTS

Works Number Time (Hour) Workload (Hour)
Course Related Works
Class Time (Exam weeks are excluded) 14 3 42
Out of Class Study (Preliminary Work, Practice) 14 4 56
Assesment Related Works
Homeworks, Projects, Others 1 10 10
Mid-term Exams (Written, Oral, etc.) 1 15 15
Final Exam 1 30 30
Total Workload (Hour) 153
Total Workload / 25 (h) 6,12
ECTS 6 ECTS

Update Time: 10.05.2024 12:09